in my experience polyester is harder
you can usually just dig a finger nail into sun warmed epoxy but you never can into polyester
epoxy is the best for wood, it's easier to mix, the chemicals aren't as dangerous and the fumes nowhere near as bad
but for repairs to polyester boats polyester bonds better, is harder and cheaper
keep in mind the polyester reaction requires a "Kick" from a small toxic catalyst and that the surface chemical left over from the epoxy reaction inhibit this kick
so if someone does a small epoxy repair to a normal polyester boat but later wants to spray new gelcoat over it the gelcoat over the epoxy won't cure correctly if at all