| Carbon Fiber Composites -Do they age? #258346 03/15/13 11:00 PM 03/15/13 11:00 PM |
Joined: Jun 2001 Posts: 493 Minnesota Jeff Peterson OP
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Posts: 493 Minnesota | Carbon fiber composites have been around for awhile, now. So if there is going to be aging problems, I would think it is about time for problems to start showing up. Has anyone noticed problems like delamination, fatigue, crazing, erosion, or embrittlement?
Jeff Peterson H-16 Sail #23721 Big Marine Lake, MN
| | | Re: Carbon Fiber Composites -Do they age?
[Re: Jeff Peterson]
#258377 03/17/13 10:21 AM 03/17/13 10:21 AM |
Joined: Sep 2002 Posts: 3,224 Roanoke Island ,N.C. Team_Cat_Fever
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Posts: 3,224 Roanoke Island ,N.C. | UV is your biggest enemy.
"I said, now, I said ,pay attention boy!"
The cure for anything is salt water - sweat, tears, or the sea Isak Dinesen If a man is to be obsessed by something.... I suppose a boat is as good as anything... perhaps a bit better than most. E. B. White
| | | Re: Carbon Fiber Composites -Do they age?
[Re: Team_Cat_Fever]
#258378 03/17/13 12:29 PM 03/17/13 12:29 PM |
Joined: Jun 2009 Posts: 524 Petten Netherlands northsea junkie
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Posts: 524 Petten Netherlands | UV is your biggest enemy. UV is the biggest enemy for the (epoxy-)resin, not for the carbon tissue itself. Nevertheless unprotected black carbon/resin laminate will heatup considerably in the sun.
ronald RAIDER-15 (homebuilt)
hey boy, what did you do over there, alone far out at sea?.. "huh....., that's the only place where I'm happy, sir.
| | | Re: Carbon Fiber Composites -Do they age?
[Re: Jeff Peterson]
#258382 03/17/13 04:01 PM 03/17/13 04:01 PM | Scarecrow
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1. wrong resin: Using too stiff a reason (ie polyester) will result in the matrix breaking down and delaminating. Can be prevented by always using epoxy.
2. UV damage can cause the resin to break down and wait for it.... delaminate. Can be prevented by painting with a suitable paint, so stop posing and loose the clear carbon.
3. Getting too hot can cause the resin to soften and re-distribute itself in the matrix, so make sure the above paint is white.
4. Too much resin will make it harder and can cause it to crack as per 1. above. So worst case weigh out your resin, best case use infusion or pre-preg.
5. Not enough resin means the fibers wont be held together properly and they'll delaminate when loaded. See above for fix. | | | Re: Carbon Fiber Composites -Do they age?
[Re: northsea junkie]
#258385 03/17/13 05:29 PM 03/17/13 05:29 PM |
Joined: Sep 2002 Posts: 3,224 Roanoke Island ,N.C. Team_Cat_Fever
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Posts: 3,224 Roanoke Island ,N.C. | UV is your biggest enemy. UV is the biggest enemy for the (epoxy-)resin, not for the carbon tissue itself. Nevertheless unprotected black carbon/resin laminate will heatup considerably in the sun. OK Capt. Semantics, carbon fiber parts aren't much use without the resin now are they?
"I said, now, I said ,pay attention boy!"
The cure for anything is salt water - sweat, tears, or the sea Isak Dinesen If a man is to be obsessed by something.... I suppose a boat is as good as anything... perhaps a bit better than most. E. B. White
| | | Re: Carbon Fiber Composites -Do they age?
[Re: Team_Cat_Fever]
#258391 03/18/13 03:26 AM 03/18/13 03:26 AM |
Joined: Jun 2009 Posts: 524 Petten Netherlands northsea junkie
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Posts: 524 Petten Netherlands | [/quote] OK Capt. Semantics, carbon fiber parts aren't much use without the resin now are they? [/quote] What I ment to say is that for the carbonfibre composite there isn't much difference with the good oldfashioned glass composite. The "weak" component remains the resin: UV detoriation, critical for weight ratio tissue/resin, hardening complications (moisture,etc), after-hardening, etc. Sometimes people forget that the only function of the resin is keeping the filaments of the glass/carbon/kevlar/orwhatever tissue together and in place. This requires a very specific close-fitting fabrication of any composite. So from this point of view there isn't much difference between glass and carbon laminates. A lot laymen think that Carbonfibre composites are some kind of miracle material (well it is invented in aerospace-industry), but it isn't. It has the same usual disadvantages as all the other composites (infact even more). For the rest, I'm all in what Scarecrow wrote above.
Last edited by northsea junkie; 03/18/13 05:16 AM.
ronald RAIDER-15 (homebuilt)
hey boy, what did you do over there, alone far out at sea?.. "huh....., that's the only place where I'm happy, sir.
| | | Re: Carbon Fiber Composites -Do they age?
[Re: northsea junkie]
#258619 03/29/13 10:10 PM 03/29/13 10:10 PM |
Joined: Jun 2001 Posts: 493 Minnesota Jeff Peterson OP
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Posts: 493 Minnesota | Hmm..., I was expecting to at least get a little controversy out of this posting. Not even one bad experience out there with carbon fiber? --All I got was a lecture from the wissened sailing elders to the ignorant masses, about the basics of boat construction. I guess that's a good sign that there haven't been any real problems specific to carbon composites. The U.S. Airforce has to hide their Stealth airplanes in buildings, because the weather and sun damages them. Must not be a problem for sailboats. --Must be the white paint.
Jeff Peterson H-16 Sail #23721 Big Marine Lake, MN
| | | Re: Carbon Fiber Composites -Do they age?
[Re: Jeff Peterson]
#258621 03/29/13 10:53 PM 03/29/13 10:53 PM |
Joined: Jan 2004 Posts: 1,884 Detroit, MI mbounds
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Posts: 1,884 Detroit, MI | The U.S. Airforce has to hide their Stealth airplanes in buildings, because the weather and sun damages them. Has nothing to do with carbon fiber and everything to do with the RAM (radar absorbent material) used to cover the plane's skin. | | | Re: Carbon Fiber Composites -Do they age?
[Re: waynemarlow]
#258629 03/30/13 04:23 PM 03/30/13 04:23 PM |
Joined: Aug 2007 Posts: 1,304 Gulf Coast relocated from Cali... TeamChums
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Posts: 1,304 Gulf Coast relocated from Cali... | My carbon N20 mast has taken 12 years of abuse now. We bend the hell out of it with double trap spinn reaching. I even ease the main ALOT in the puffs to keep from driving off. It's a Southern Spars mast, which I believe is a little stiffer than the other ones. I think keeping it protected with the paint is key.
Lee
Keyboard sailors are always faster in all conditions.
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[Re: ]
#258630 03/30/13 05:08 PM 03/30/13 05:08 PM |
Joined: Jun 2001 Posts: 1,449 phill
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Posts: 1,449 | In addition to what has been said already:-
I know that at least some good quality pre pregs have UV inhibitors in the resin to protect from UV.
Also a good quality pre preg will have a relatively high cure temp and if you elevate the cure temp, in accordance with resin recommendation, towards the end of the cure cycle that can help the laminate withstand extremes of heat caused by the sun.
If you are not using pre preg get a resin with data sheets that detail the vacuum window. Weigh everything and follow the data sheets to avoid resin starvation in the laminate. Alternatively don't pull too high a vacuum. Also post cure the laminate but I would still paint it white.
If you did not make it yourself and not privy to all the details paint it white.
I know that the voices in my head aint real, but they have some pretty good ideas. There is no such thing as a quick fix and I've never had free lunch!
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[Re: ]
#258631 03/30/13 08:19 PM 03/30/13 08:19 PM |
Joined: Apr 2012 Posts: 190 Bille
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Posts: 190 | ...
3. Getting too hot can cause the resin to soften and re-distribute itself in the matrix, so make sure the above paint is white.
4. Too much resin will make it harder and can cause it to crack as per 1. above. So worst case weigh out your resin, best case use infusion or pre-preg. ...
#3) the heat "WILL" also cause your foam-core to melt !! another reason for white paint. I use Nomex-Honeycomb so i don't care about that one, UV inhibitors will work. to protect the resin though, if Ya like that Carbon look ! #4) Weigh the resin like the man said (1-gram of fiber TO 1-gram of resin) spread it out then get rid of 15% of the resin with shop-towels wrapped around toilet-paper ; Or use Peal-Ply & baby-blanket under the vacuum bag. Too much resin will cause the lamination's to FLOAT with epoxy between ; this causes the Epoxy to act like a core material so as to add thickness. NOT GOOD because the epoxy is kinda brittle so it breaks down between the fibers. A Quality core increases the strength by the (3) of the thickness. Bille | | | Re: Carbon Fiber Composites -Do they age?
[Re: carlbohannon]
#258648 04/01/13 11:18 AM 04/01/13 11:18 AM |
Joined: Dec 2001 Posts: 5,590 Naples, FL waterbug_wpb
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Posts: 5,590 Naples, FL | I'm too lazy to look, but can you recycle composite materials once it's past its useful life?
It doesn't melt? Would burning it produce more problems than it's worth (for the heat output)? Crushing/grinding? Any use for the product? (at least it wouldn't take up as much landfill space as a powder than a partially deconstructed hull/mast)
Jay
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[Re: Jeff Peterson]
#258650 04/01/13 12:12 PM 04/01/13 12:12 PM |
Joined: Jan 2009 Posts: 5,525 pgp
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Posts: 5,525 | Ofcourse it melts! Below the boiling point of water, maybe 180 iirc. 20+ years ago I was warned to never anchor over a volcano!
Last edited by pgp; 04/01/13 12:14 PM.
Pete Pollard Blade 702
'When you have a lot of things to do, it's best to get your nap out of the way first.
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[Re: carlbohannon]
#258652 04/01/13 01:52 PM 04/01/13 01:52 PM |
Joined: Jun 2009 Posts: 524 Petten Netherlands northsea junkie
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Posts: 524 Petten Netherlands | Every time you apply a full load cycle to a composite, you get some level of micro delamination. In theory the designer should determine what loads it must handle and what lifetime they want and back out the laminate. This is true for all plastic laminates and aluminum. Steel is different. Carbon and aluminum crack and fall apart. Steel gets flexy. In Engineering this usually lumped under fatigue.
The micro-delamination of a carbon-composite in a load-cycle, I don't quite understand. Nor the aluminium vulnerability. If you stay with your loads far within the maximum tension values( I forgot the correct technical english for that), you don't damage the molecullar structure, aren't you???????? So, no hairline-cracks, no delamination, etc. Besides, the aluminium fatigue I know, has often to do with outside surface-erosion (or inside; in closed tubes-constructions, like bicycles) Is it not that this phenomenon which you describe, only applies for the situation that you pass now and then unforseenly and unwanted the stress-values of your material.?????????
Last edited by northsea junkie; 04/01/13 02:35 PM.
ronald RAIDER-15 (homebuilt)
hey boy, what did you do over there, alone far out at sea?.. "huh....., that's the only place where I'm happy, sir.
| | | Re: Carbon Fiber Composites -Do they age?
[Re: northsea junkie]
#258666 04/02/13 10:34 AM 04/02/13 10:34 AM |
Joined: Jun 2001 Posts: 778 Houston carlbohannon
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Posts: 778 Houston | Steel and Titanium behave like you described. As long as you keep the load below tbd% of yield, there is no cycle limit. Aluminum and composites have a fatigue limit. Aluminum fatigue is well documented with Airliners. (Remember the aircraft on TV that failed because they exceeded the pressurization cycles or Landing Cycles without making mods to extend their life?) Heavy flexible composite have a very very long fatigue life. The stuff from the 90's was assumed to have an infinite cycle life. Stiff light composites with only just enough of the right material in the right place have a shorter life. Composites also have a problem with crack propagation. If you hit it in a way it was not designed for, it cracks and the crack propagates until it fails. easy to read: http://en.wikipedia.org/wiki/Fatigue_limithttp://www.airliners.net/aviation-forums/tech_ops/read.main/91016/Not easy to read, what the experts say to me http://books.google.com/books?id=FW...e%20of%20carbon%20composites&f=falsehttp://scholar.lib.vt.edu/theses/av...Part_2_strength_and_life_predictions.pdfGoogle "composite fatigue life predictions" and you will find plenty of technical articles and Conference Paper Reprints. There is a lot of information in the Public Information of the FAA. This is not my area of expertise. I can't argue with you. Everything I have seen below the PHD level is proprietary. The only article on the subject, I know of was in, I think, Mountain Bike Action in the Fall of 2011. I showed it to 2 world class experts and they both said if their assumptions about the life of the aluminum frame is correct, it looks about right. I canceled an order for a super light carbon frame and bought a heavier aluminum one. | | | Re: Carbon Fiber Composites -Do they age?
[Re: Jeff Peterson]
#258679 04/02/13 12:56 PM 04/02/13 12:56 PM |
Joined: Jun 2009 Posts: 524 Petten Netherlands northsea junkie
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Posts: 524 Petten Netherlands | Thanks Carl, for this clarifying and comprehensive information you gave me.
The first and most striking eye-opener for me to read was the notice that fibre composites are by nature inhomogeneous (resin and fibres) and anisotropic (=not as strong in each direction).
This very fact alone will always create fatigue!!!
I've never realized that.
ronald RAIDER-15 (homebuilt)
hey boy, what did you do over there, alone far out at sea?.. "huh....., that's the only place where I'm happy, sir.
| | | Re: Carbon Fiber Composites -Do they age?
[Re: northsea junkie]
#258688 04/02/13 07:16 PM 04/02/13 07:16 PM |
Joined: Jun 2001 Posts: 12,310 South Carolina Jake
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The first and most striking eye-opener for me to read was the notice that fibre composites are by nature inhomogeneous (resin and fibres) and anisotropic (=not as strong in each direction).
Yes, this is part of the benefit in that you can build strength vs. flexibility in particular directions in a solid laminate. America's cup teams use this to great detail. Composite spar manufactures use this function in every mast they build.
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